Reductive dechlorination of chlorophenols by a pentachlorophenol- acclimated methanogenic consortium
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چکیده
منابع مشابه
Comparison of reactors for oxygen-sensitive reactions: reductive dechlorination of chlorophenols by vitamin b(12s).
Serum bottles are frequently used for studies of reductive dechlorination by vitamin B(12), but reducing conditions can be maintained only for several days. This time period is inadequate for evaluating the reductive dechlorination of some slow-reacting aromatic compounds. Sealed glass ampoules maintain reducing conditions for many months, but this method has the disadvantage of disallowing sub...
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Tetrachloroethene (PCE) and other chloroethenes are major contaminants in groundwater, and PCE is particularly resistant to attack by aerobes. We have developed an anaerobic enrichment culture that carries out reductive dechlorination of chloroethenes to ethene at high rates, thereby detoxifying them. Although the electron donor added to the culture is methanol, our evidence indicates that H2 i...
متن کاملRegiospecificity of chlorophenol reductive dechlorination by vitamin b(12s).
Vitamin B(12), reduced by titanium (III) citrate to vitamin B(12s), catalyzes the reductive dechlorination of chlorophenols. Reductive dechlorination of pentachlorophenol and of all tetrachlorophenol and trichlorophenol isomers was observed. Reaction of various chlorophenols with vitamin B(12) favored reductive dechlorination at positions adjacent to another chlorinated carbon, but chlorines or...
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Simultaneous anaerobic and aerobic degradation pathways in two-chamber, tubular microbial fuel cells (MFCs) facilitated pentachlorophenol (PCP) mineralization by a mediator-less biocathode. PCP was degraded at a rate of 0.263 ± 0.05 mg/L-h (51.5 mg/g VSS-h) along with power generation of 2.5 ± 0.03 W/m(3). Operating the biocathode MFC at 50°C improved the PCP degradation rate to 0.523 ± 0.08 mg...
متن کاملRole of methanogenic and sulfate-reducing bacteria in the reductive dechlorination of tetrachloroethylene in mixed culture.
Several reports have demonstrated biotransformation of tetrachloroethylene at low concentrations under strict anaerobic conditions by sequential reductive dechlorination (Fathepure and Boyd, 1988a; Freedman and Gosset, 1989). During this biodegradation, trichloroethylene (TCE), 1,1dichloroethylene, vinylidene chloride (DCE), and vinyl chloride (VC) are the intermediate products ; ethene or etha...
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ژورنال
عنوان ژورنال: Applied and Environmental Microbiology
سال: 1992
ISSN: 0099-2240,1098-5336
DOI: 10.1128/aem.58.7.2280-2286.1992